Vented Gas Fireplaces

Perfect Gas ... A thermally perfect gas is in thermodynamic equilibrium is not chemically reacting has internal energy e, enthalpy h, and specific heat Cv that are functions of temperature only and not of pressure, i.e., ... This type of approximation is useful for modeling, for example, an axial compressor where temperature fluctuations are usually not large enough to cause any significant deviations from the thermally perfect gas model... Even more restricted is the calorically perfect gas for which, in addition, the specific heat is assumed to be constant: and ...

Avogadro's Law ... Thus, the number of molecules or atoms in a specific volume of gas is independent of their size or the molar mass of the gas... As an example, equal volumes of molecular hydrogen and nitrogen contain the same number of molecules when they are at the same temperature and pressure, and observe ideal gas behavior... Mathematical definition Avogadro's law is stated mathematically as: Where: V is the volume of the gas...

Gasification ... Syngas may be burned directly in gas engines, used to produce methanol and hydrogen, or converted via the Fischer-Tropsch process into synthetic fuel... In addition, the high-temperature process refines out corrosive ash elements such as chloride and potassium, allowing clean gas production from otherwise problematic fuels... Initially developed to produce town gas for lighting & cooking in 1800s, this was replaced by electricity and natural gas, it was also used in blast furnaces but the bigger role was played in the production of synthetic chemicals where it has been in use since the 1920s...

Gas ... High-density atomic gases super cooled to incredibly low temperatures are classified by their statistical behavior as either a Bose gas or a Fermi gas... Their detailed studies ultimately led to a mathematical relationship among these properties expressed by the ideal gas law (see simplified models section below)... Gas particles are widely separated from one another, and as such are not as strongly intermolecularly bonded to the same degree as liquids or solids...

Thermodynamic Equilibrium ... Thermodynamics Branches Classical · Statistical · Chemical Equilibrium / Non-equilibrium Thermofluids Laws Zeroth · First · Second · Third Systems State: Equation of state Ideal gas · Real gas Phase of matter · Equilibrium Control volume · Instruments Processes: Isobaric · Isochoric · Isothermal Adiabatic · Isentropic · Isenthalpic Quasistatic · Polytropic Free expansion Reversibility · Irreversibility Endoreversibility Cycles: Heat engines · Heat pumps Thermal efficiency System properties Property diagrams Intensive and extensive properties State functions: Temperature / Entropy (intro.) † Pressure / Volume † Chemical potential / Particle no... † († Conjugate variables) Vapor quality Reduced properties Process functions: Work · Heat Material properties Specific heat capacity Compressibility Thermal expansion...

Future Car Technologies ... With rising gas prices, the future of the automobile is now leaning towards fuel efficiency, energy-savers, hybrid vehicles, battery electric vehicles, and fuel-cell vehicles...

History Of The Automobile ... The first automobile patent in the United States was granted to Oliver Evans in 1789. 19th century Among other efforts, in 1815, a professor at Prague Polytechnich, Josef Bozek, built an oil-fired steam car...

Real Gas ... Where P is the pressure, T is the temperature, R the ideal gas constant, and Vm the molar volume. a and b are parameters that are determined empirically for each gas, but are sometimes estimated from their critical temperature (Tc) and critical pressure (Pc) using these relations:...

Kinetic Theory ... While the particles making up a gas are too small to be visible, the jittering motion of pollen grains or dust particles which can be seen under a microscope, known as Brownian motion, results directly from collisions between the particle and gas molecules... Postulates The theory for ideal gases makes the following assumptions: The gas consists of very small particles... This smallness of their size is such that the total volume of the individual gas molecules added up is negligible compared to the volume of the container...

Turbulence ... Irregularity: Turbulent flows are always highly irregular. This is why turbulence problems are always treated statistically rather than deterministically...

Statistical Mechanics ... Statistical mechanics was initiated in 1870 with the work of Austrian physicist Ludwig Boltzmann, much of which was collectively published in Boltzmann's 1896 Lectures on Gas Theory...

Equation Of State ... The pressure of the gas could be determined by the difference between the mercury level in the short end of the tube and that in the long, open end... Mathematically, this can be represented for n species as: The ideal gas law (1834) In 1834 Émile Clapeyron combined Boyle's Law and Charles' law into the first statement of the ideal gas law... Initially the law was formulated as pVm = R (TC + 267) (with temperature expressed in degrees Celsius), where R is the gas constant...

Brownian Motion ... In 1827 the biologist Robert Brown noticed that if you looked at pollen grains in water through a microscope, the pollen jiggles about. He called this jiggling 'Brownian motion', but Brown couldn't work out what was causing it...

Thermodynamic Temperature ... At its simplest, temperature arises from the kinetic energy of the vibrational motions of matter's particle constituents (molecules, atoms, and subatomic particles). The full variety of these kinetic motions, along with potential energies of particles, and also occasionally certain other types of particle energy in equilibrium with these, contribute the total thermal energy (loosely, the heat energy) within a substance...

Second Generation Biofuels ... Many first generation biofuels are dependent of subsidies and are not cost competitive with existing fossil fuels such as oil, and some of them produce only limited greenhouse gas emissions savings...

Density ... Less dense fluids float on more dense fluids if they do not mix. This concept can be extended, with some care, to less dense solids floating on more dense fluids...

Boyle's Law ... As improvements in technology permitted higher pressures and lower temperatures, deviations from the ideal gas behavior became noticeable, and the relationship between pressure and volume can only be accurately described employing real gas theory...

Viscosity ... Viscosity describes a fluid's internal resistance to flow and may be thought of as a measure of fluid friction. For example, high-viscosity felsic magma will create a tall, steep stratovolcano, because it cannot flow far before it cools, while low-viscosity mafic lava will create a wide, shallow-sloped shield volcano...

Fossil Fuel ... It was estimated by the Energy Information Administration that in 2007 primary sources of energy consisted of petroleum 36.0%, coal 27.4%, natural gas 23.0%, amounting to an 86.4% share for fossil fuels in primary energy consumption in the world...