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Dalton's Law ... Mathematically, the pressure of a mixture of gases can be defined as the summation or where represent the partial pressure of each component. It is assumed that the gases do not react with each other...
Charles's Law ... His statement of the law can be expressed mathematically as: where V100 is the volume occupied by a given sample of gas at 100 °C; V0 is the volume occupied by the same sample of gas at 0 °C; and k is a constant which is the same for all gases at constant pressure...
MOX Fuel ... One attraction of MOX fuel is that it is a way of utilizing surplus weapons-grade plutonium, an alternative to storage of surplus plutonium, which would need to be secured against the risk of theft for use in nuclear weapons. On the other hand, some studies warned that normalising the global commercial use of MOX fuel and the associated expansion of nuclear reprocessing will increase, rather than reduce, the risk of nuclear proliferation, by encouraging increased separation of plutonium from spent fuel in the civil nuclear fuel cycle...
Real Gas ... Where P is the pressure, T is the temperature, R the ideal gas constant, and Vm the molar volume. a and b are parameters that are determined empirically for each gas, but are sometimes estimated from their critical temperature (Tc) and critical pressure (Pc) using these relations:...
Compressibility Factor ... In many real world applications requirements for accuracy demand that deviations from ideal gas behaviour, i.e., real gas behaviour, is taken into account... This allows repulsive forces between molecules to have a noticeable effect, making the molar volume of the real gas greater than the molar volume of the corresponding ideal gas, which causes to exceed one... The closer the gas is to its critical point or its boiling point, the more deviates from the ideal case...
Pressure ... It is incorrect (although rather usual) to say "the pressure is directed in such or such direction". The pressure, as a scalar, has no direction...
Van Der Waals Force ... All intermolecular/van der Waals forces are anisotropic (except those between two noble gas atoms), which means that they depend on the relative orientation of the molecules... When molecules are in thermal motion, as they are in the gas and liquid phase, the electrostatic force is averaged out to a large extent, because the molecules thermally rotate and thus probe both repulsive and attractive parts of the electrostatic force...
Biofuel ... Bioethanol is an alcohol made by fermentation, mostly from carbohydrates produced in sugar or starch crops such as corn or sugarcane. Cellulosic biomass, derived from non-food sources such as trees and grasses, is also being developed as a feedstock for ethanol production...
Thermodynamics ... Thermodynamics can be applied to a wide variety of topics in science and engineering, such as engines, phase transitions, chemical reactions, transport phenomena, and even black holes. The results of thermodynamics are essential for other fields of physics and for chemistry, chemical engineering, aerospace engineering, mechanical engineering, cell biology, biomedical engineering, materials science, and are useful for other fields such as economics...
Kinetic Theory ... While the particles making up a gas are too small to be visible, the jittering motion of pollen grains or dust particles which can be seen under a microscope, known as Brownian motion, results directly from collisions between the particle and gas molecules... Postulates The theory for ideal gases makes the following assumptions: The gas consists of very small particles... This smallness of their size is such that the total volume of the individual gas molecules added up is negligible compared to the volume of the container...
Brownian Motion ... In 1827 the biologist Robert Brown noticed that if you looked at pollen grains in water through a microscope, the pollen jiggles about. He called this jiggling 'Brownian motion', but Brown couldn't work out what was causing it...
Perfect Gas ... A thermally perfect gas is in thermodynamic equilibrium is not chemically reacting has internal energy e, enthalpy h, and specific heat Cv that are functions of temperature only and not of pressure, i.e., ... This type of approximation is useful for modeling, for example, an axial compressor where temperature fluctuations are usually not large enough to cause any significant deviations from the thermally perfect gas model... Even more restricted is the calorically perfect gas for which, in addition, the specific heat is assumed to be constant: and ...
Nuclear Fuel ... Most nuclear fuels contain heavy fissile elements that are capable of nuclear fission. When these fuels are struck by neutrons, they are in turn capable of emitting neutrons when they break apart...
Boyle's Law ... As improvements in technology permitted higher pressures and lower temperatures, deviations from the ideal gas behavior became noticeable, and the relationship between pressure and volume can only be accurately described employing real gas theory...
Equation Of State ... The pressure of the gas could be determined by the difference between the mercury level in the short end of the tube and that in the long, open end... Mathematically, this can be represented for n species as: The ideal gas law (1834) In 1834 Émile Clapeyron combined Boyle's Law and Charles' law into the first statement of the ideal gas law... Initially the law was formulated as pVm = R (TC + 267) (with temperature expressed in degrees Celsius), where R is the gas constant...
Effects Of The Automobile On Societies ... The effects of the automobile on everyday life have been a subject of controversy. While the introduction of the mass-produced automobile represented a revolution in mobility and convenience, the modern consequences of heavy automotive use contribute to the use of non-renewable fuels, a dramatic increase in the rate of accidental death, social isolation, the disconnection of community, the rise in obesity, the generation of air & noise pollution, urban sprawl, and urban decay...
Statistical Mechanics ... Statistical mechanics was initiated in 1870 with the work of Austrian physicist Ludwig Boltzmann, much of which was collectively published in Boltzmann's 1896 Lectures on Gas Theory...
Thermodynamic Temperature ... At its simplest, temperature arises from the kinetic energy of the vibrational motions of matter's particle constituents (molecules, atoms, and subatomic particles). The full variety of these kinetic motions, along with potential energies of particles, and also occasionally certain other types of particle energy in equilibrium with these, contribute the total thermal energy (loosely, the heat energy) within a substance...
History Of The Automobile ... The first automobile patent in the United States was granted to Oliver Evans in 1789. 19th century Among other efforts, in 1815, a professor at Prague Polytechnich, Josef Bozek, built an oil-fired steam car...
Fuel ... Perhaps the earliest fuel employed by humans is wood. Evidence shows controlled fire was used up to 1.5 million years ago at Swartkrans, South Africa...
Gay-Lussac's Law ... In addition to Gay-Lussac's results, Amedeo Avogadro theorized that, at the same temperature and pressure, equal volumes of gas contain equal numbers of molecules (Avogadro's law)... Pressure-temperature law Gay-Lussac's name is also associated — erroneously — with another gas law, the so-called pressure law, which states that:...