Statistical Mechanics ... Statistical mechanics was initiated in 1870 with the work of Austrian physicist Ludwig Boltzmann, much of which was collectively published in Boltzmann's 1896 Lectures on Gas Theory...
Thermodynamic Equilibrium ... Thermodynamics Branches Classical · Statistical · Chemical Equilibrium / Non-equilibrium Thermofluids Laws Zeroth · First · Second · Third Systems State: Equation of state Ideal gas · Real gas Phase of matter · Equilibrium Control volume · Instruments Processes: Isobaric · Isochoric · Isothermal Adiabatic · Isentropic · Isenthalpic Quasistatic · Polytropic Free expansion Reversibility · Irreversibility Endoreversibility Cycles: Heat engines · Heat pumps Thermal efficiency System properties Property diagrams Intensive and extensive properties State functions: Temperature / Entropy (intro.) † Pressure / Volume † Chemical potential / Particle no... † († Conjugate variables) Vapor quality Reduced properties Process functions: Work · Heat Material properties Specific heat capacity Compressibility Thermal expansion...
Automobile ... The term motorcar has also been used in the context of electrified rail systems to denote a car which functions as a small locomotive but also provides space for passengers and baggage. These locomotive cars were often used on suburban routes by both interurban and intercity railroad systems...
Biofuel ... Bioethanol is an alcohol made by fermentation, mostly from carbohydrates produced in sugar or starch crops such as corn or sugarcane. Cellulosic biomass, derived from non-food sources such as trees and grasses, is also being developed as a feedstock for ethanol production...
Kinetic Theory ... While the particles making up a gas are too small to be visible, the jittering motion of pollen grains or dust particles which can be seen under a microscope, known as Brownian motion, results directly from collisions between the particle and gas molecules... Postulates The theory for ideal gases makes the following assumptions: The gas consists of very small particles... This smallness of their size is such that the total volume of the individual gas molecules added up is negligible compared to the volume of the container...
Behavior Of Nuclear Fuel During A Reactor Accident ... According to one paper the following difference between the cladding failure mode of unused and used fuel was seen. Unirradiated fuel rods were pressurized before being placed in a special reactor at the Japanese Nuclear Safety Research Reactor (NSRR) where they were subjected to a simulated RIA transient...
Dalton's Law ... Mathematically, the pressure of a mixture of gases can be defined as the summation or where represent the partial pressure of each component. It is assumed that the gases do not react with each other...
Van Der Waals Force ... All intermolecular/van der Waals forces are anisotropic (except those between two noble gas atoms), which means that they depend on the relative orientation of the molecules... When molecules are in thermal motion, as they are in the gas and liquid phase, the electrostatic force is averaged out to a large extent, because the molecules thermally rotate and thus probe both repulsive and attractive parts of the electrostatic force...
Nuclear Fuel ... Most nuclear fuels contain heavy fissile elements that are capable of nuclear fission. When these fuels are struck by neutrons, they are in turn capable of emitting neutrons when they break apart...
Alternative Fuel Vehicle ... 14.7 million natural gas vehicles by December 2011, led by Iran with 2.86 million, Pakistan (2.85 million), Argentina (2.04 million), Brazil (1.7 million), and India (1.1 million)...
Gay-Lussac's Law ... In addition to Gay-Lussac's results, Amedeo Avogadro theorized that, at the same temperature and pressure, equal volumes of gas contain equal numbers of molecules (Avogadro's law)... Pressure-temperature law Gay-Lussac's name is also associated — erroneously — with another gas law, the so-called pressure law, which states that:...
Future Car Technologies ... With rising gas prices, the future of the automobile is now leaning towards fuel efficiency, energy-savers, hybrid vehicles, battery electric vehicles, and fuel-cell vehicles...
Real Gas ... Where P is the pressure, T is the temperature, R the ideal gas constant, and Vm the molar volume. a and b are parameters that are determined empirically for each gas, but are sometimes estimated from their critical temperature (Tc) and critical pressure (Pc) using these relations:...
Charles's Law ... His statement of the law can be expressed mathematically as: where V100 is the volume occupied by a given sample of gas at 100 °C; V0 is the volume occupied by the same sample of gas at 0 °C; and k is a constant which is the same for all gases at constant pressure...
Compressibility Factor ... In many real world applications requirements for accuracy demand that deviations from ideal gas behaviour, i.e., real gas behaviour, is taken into account... This allows repulsive forces between molecules to have a noticeable effect, making the molar volume of the real gas greater than the molar volume of the corresponding ideal gas, which causes to exceed one... The closer the gas is to its critical point or its boiling point, the more deviates from the ideal case...